D.A Evans 哈佛大学化学系教授,曾获得06年化学诺贝尔奖
下是Evans编写的高等有机化学课程,由于是自己亲自带课,所以Evans教授写的讲义更注重最新课题研究和实际问题的结合,此讲义非常深刻,简洁.适合阅读过高等有机或者基础较好的竞赛学生参考

因为小a跟我说过多次如何买高等有机化学,可惜最近太忙也无从查考,March的高等有机化学要几十兆到几百兆也传不上来,这份Evans也算是不错的教材,算是给小a和大家献礼,这组课程一共36个课时,大约是研究生1年课时,包括近一百篇相关文献和十几张测试,课程全面深入,个人比较喜欢,经过我的整理也算是成了一个系列,所以算是我个人的珍藏吧,所以要多加一些权限给高等级的坛友共享

这里Lecture Literature Seminar Topic 分别用不同字体让大家看的清楚一些

在发完前我要锁定帖子,待发完后可以发言讨论问题
Lecture1:
An Introduction to Frontier Molecular Orbital Theory
General Bonding Considerations
The H2 Molecule Revisited
Donor & Acceptor Properties of Bonding & Antibonding States
Hyperconjugation and "Negative" Hyperconjugation
Anomeric and Related Effects

[ 本帖最后由 墨菲斯托同学 于 2008-6-28 18:34 编辑 ]

Lecture2 literature:
A Simple Qualitative Molecular-Orbital/Valence-Bond
Description of the Bonding in Main Group “Hypervalent” Molecules

Leture2:
Stereoelectronic Effects-1
Anomeric and Related Effects
Electrophilic & Nucleophilic Substitution Reactions
The SN2 Reaction: Stereoelectronic Effects
Olefin Epoxidation: Stereoelectronic Effects
Baeyer-Villiger Reaction: Stereoelectronic Effects
Olefin Bromination: Stereoelectronic Effects
Hard & Soft Acid and Bases

Lecture3 literature
Brauman.pdf
Steric Effects and Solvent Effects in Ionic Reactions
Crudden.pdf   
Adolf Baeyer and Victor Villiger Reaction
Dioxirane_Epoxidations.pdf   
The Development of Dioxirane Mediated
Enantioselective Epoxidation Reactions
• Introduction to Dioxiranes
• Early Epoxidations
• Initial Asymmetric Epoxidations
• Recent Advances, focusing on the Shi Group
Fukui.pdf   
Recognition of Stereochemical Paths by Orbital Interaction
Kishi..pdf
Experimental Support for the Primary
Stereoelectronic Effect Governing Baeyer-Villiger
Oxidation and Criegee Rearrangement
Shi.pdf   
Chiral Ketone-Catalyzed Asymmetric Epoxidation of Olefins

Lecture3:
Stereoelectronic Effects-2
Rules for Ring Closure

Lecture3 seminar
Steric, Electronic, & Conformational Effects in Epoxide–Nucleophile Reactions

Lecture4
Acyclic Conformational Analysis-1
Ethane, Propane, Butane & Pentane Conformations
Introduction to Allylic Strain

Lecture4 literature
Ethaneconf.pdf
A new twist on molecular shape
Hoffmann.pdf   
Conformation Design of Open-Chain Compounds
HoffmannCR.pdf   
Allylic 1 ,&Strain as a Controlling Factor in Stereoselective Transformations

Lecture5:
Acyclic Conformational Analysis-2
Conformations of Simple Olefinic Substrates
Introduction to Allylic Strain
Introduction to Allylic Strain-2: Amides and Enolates

Lecture6:
Conformational Analysis-3
Cyclopropane
Conformational Analysis of C4  ® C8 Rings

Lecture6 literature
Snyder.pdf   
The Unexpected Diaxial Orientation of
cis-3,5-Difluoropiperidine in Water: A Potent
CF- - -NH Charge-Dipole Effect

Lecture7
Conformational Analysis-4
Conformational Analysis of C6  ® C8 Rings continued
Curtin–Hammett Principle

Lecture7 literature:
Houk.pdf   
Theory and Modeling of Stereoselective Organic Reactions

Lecture8:
Olefin Addition Reactions–1
Hydroboration
Epoxidation & Directed Epoxidation

Lecture8 literature:
Houk-Tet.pdf   
Theoretical Studies of Stereoselective Hydroborations

Lecture9:
Olefin Addition Reactions–2
Epoxidation & Directed Epoxidation
Hydrogenation
Hydride Reduction

Lecture9 seminar
Synthetic & Mechanistic Overview of Electrophilic Halogenation

Lecture9 literature:
Schreiner.pdf
Lessons from the Mistaken Origin of the Rotational Barrier in Ethane

Lecture10:
Olefin Addition Reactions–3
Olefin Bromination
Olefin Oxymercuration
Halolactonization
Simmons-Smith Reaction

Lecture10 seminar
Diastereoselective Attack of Electrophiles on Chiral Olefins